When you make a booking with ParcelCompare, the details you provide during the booking process is used to generate your customs paperwork.
A copy of this is provided to you along with your labels in your order confirmation page and in your confirmation email, which you can then save or print.
If you have a ParcelCompare account, once you have made your booking the shipment will appear in the “My Shipments” section of your dashboard. Select the printer icon next to your shipment marked “Reprint Labels”. From there, you can save or print your customs documents with your labels.
Mostly customs invoices are submitted electronically to customs, so you don't need to print them.